112382-27-1

Basic information

• Product Name: METHYL 2-[1-(4-FLUOROPHENYL)ETHYLIDENE]-1-HYDRAZINECARBOXYLATE
• Synonyms: METHYL 2-[1-(4-FLUOROPHENYL)ETHYLIDENE]-1-HYDRAZINECARBOXYLATE
• CAS NO: 112382-27-1
• Molecular Formula: C10H11FN2O2
• Molecular Weight: 210.2
• Mol File: 112382-27-1.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: METHYL 2-[1-(4-FLUOROPHENYL)ETHYLIDENE]-1-HYDRAZINECARBOXYLATE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL 2-[1-(4-FLUOROPHENYL)ETHYLIDENE]-1-HYDRAZINECARBOXYLATE(112382-27-1)
• EPA Substance Registry System: METHYL 2-[1-(4-FLUOROPHENYL)ETHYLIDENE]-1-HYDRAZINECARBOXYLATE(112382-27-1)

Safety Data

• Hazardous Substances Data: 112382-27-1(Hazardous Substances Data)

Upstream product

• 6294-89-9 hydrazinecarboxylic acid methyl ester 

Downstream Products

• 39758-40-2 (2-oxo-2-(p-fluorophenyl)ethyl)phosphonic acid diethyl ester 
• 108290-32-0 2-(4-Fluoro-phenyl)-5-oxa-3,3a-diaza-cyclopenta[a]naphthalen-4-one 
• 112382-38-4 5-(4-Amino-phenyl)-3-(4-fluoro-phenyl)-pyrazole-1-carboxylic acid methyl ester 

Relevant articles and documents

Synthetic entry into 1-phosphono-3-azabicyclo[3.1.0]hexanes

3-Azabicyclo[3.1.0]hex-2-en-1-yl phosphonates were prepared in a five-step reaction route from β-ketophosphonates. The key steps in this sequence are an atom-transfer radical cyclization and an unforeseen lithium-halogen exchange with n-BuLi. The cyclization reaction proceeds with excellent diastereoselectivity. The resulting cyclic imines were reduced, and 3-azabicyclo[3.1.0]hexan-1-yl phosphonates were obtained.