1123890-53-8

Basic information

• Product Name: {[⁽²⁾H₅]-phenyl(4-bromophenyl)phosphino}benzoic acid
• Synonyms: {[⁽²⁾H₅]-phenyl(4-bromophenyl)phosphino}benzoic acid
• CAS NO: 1123890-53-8
• Molecular Weight: 390.157
• Mol File: 1123890-53-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: {[⁽²⁾H₅]-phenyl(4-bromophenyl)phosphino}benzoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: {[⁽²⁾H₅]-phenyl(4-bromophenyl)phosphino}benzoic acid(1123890-53-8)
• EPA Substance Registry System: {[⁽²⁾H₅]-phenyl(4-bromophenyl)phosphino}benzoic acid(1123890-53-8)

Safety Data

• Hazardous Substances Data: 1123890-53-8(Hazardous Substances Data)

Upstream product

• 1123890-52-7 (R)-tert-butyl {[⁽²⁾H₅]-phenyl(4-bromophenyl)phosphinyl}benzoate 
• 1123890-52-7 tert-butyl {[⁽²⁾H₅]-phenyl(4-bromophenyl)phosphinyl}benzoate 
• 1123890-52-7 (S)-tert-butyl {[⁽²⁾H₅]-phenyl(4-bromophenyl)phosphinyl}benzoate 

Downstream Products

• 1158081-68-5 (S)-{[⁽²⁾H₅]-phenyl(4-bromophenyl)phosphino}benzoic acid 
• 1158081-68-5 (R)-{[⁽²⁾H₅]-phenyl(4-bromophenyl)phosphino}benzoic acid 

Relevant articles and documents

Cleavage of tert-butyl benzoates with NaH in DMF: Comments on the mechanism and a simple and safe alternative procedure

The hazardous and inconvenient Schmidt procedure for tert-butyl benzoate ester cleavage by NaH in DMF has been reinvestigated. The reaction is suggested to involve BAC2 ester cleavage, facilitated by adventitious, NaH-derived NaOH, rather than the proposed E2 elimination of isobutylene by DMF-derived NaNMe2. Powdered KOH in THF is a significantly safer and simpler alternative that effects cleavage of tert-butyl benozoates, at ambient temperature, in excellent yield (94-99%). Georg Thieme Verlag Stuttgart.