112402-46-7Relevant academic research and scientific papers
On the [2,3] sigmatropic rearrangement of allylic nitro compounds
Alameda-Angulo, Celia,Quiclet-Sire, Beatrice,Schmidt, Elmar,Zard, Samir Z.
, p. 3489 - 3492 (2007/10/03)
(Chemical Equation Presented) Allylic nitro compounds undergo relatively clean [2,3] sigmatropic rearrangement upon heating in refluxing 1,2-dichlorobenzene in the presence of DABCO to give the corresponding allylic alcohols via the intermediate allylic n
Reaction of Carbanions Derived From α,β-Unsaturated Nitro Compounds With Electrophiles to Give α-Substituted Products
Ono, Noboru,Hamamoto, Isami,Kamimura, Akio,Kaji, Aritsune,Tamura, Rui
, p. 258 - 260 (2007/10/02)
The reaction of α,β-unsaturated nitro compounds with aldehydes or electron deficient olefins, in the presence of a base provides a simple method for the preparation of α-substituted allylic nitro compounds.The initially formed allylic carbanion reacts reg
