112422-45-4

Upstream product

• 13274-43-6 4-methyl-1,2,4-triazoline-3,5-dione 
• 112422-46-5 1,3-diphenylbicyclo<1.1.0>butane 
• 27396-24-3 1,3-dibromo-1,3-diphenylcyclobutane 

Downstream Products

• 112422-67-0 1,4-diphenyl-2,3-diazabicyclo<2.1.1>hex-2-ene 
• 112422-85-2 C₁₆H₁₄ 
• 112422-56-7 5-Methyl-3,5-diphenyl-4,5-dihydro-pyrazole-1-carboxylic acid methylamide 
• 112422-48-7 1,4-Diphenyl-2,3-diaza-bicyclo[2.1.1]hexane-2-carboxylic acid methylamide 

Relevant academic research and scientific papers

CYCLOBUTANEDIYLS: A NEW CLASS OF LOCALIZED BIRADICALS. SYNTHESIS AND EPR SPECTROSCOPY.

Nine triplet cyclobutanediyls (1) have been synthesized and observed by matrix isolation EPR spectroscopy. The zero-field splitting (zfs) parameters provide detailed information on the spin densities in these structures. The observed zfs values can be quantitatively modeled by using a straightforward semiempirical scheme, as long as one explicitly incorporates the spin polarization effects known to be important in radicals such as allyl and benzyl. In addition, interpretable hyperfine coupling (hfc) has been observed in many cyclobutanediyls. Spectral simulation produces the hfc constants, which provide further information on spin distribution and indicate that the four-membered ring in 1 is planar.