112449-52-2

Basic information

• Product Name: (-)-α-(4-biphenylmercapto)propionic acid p-phenylphenacyl ester
• CAS NO: 112449-52-2
• Molecular Weight: 452.574
• Mol File: 112449-52-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (-)-α-(4-biphenylmercapto)propionic acid p-phenylphenacyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-α-(4-biphenylmercapto)propionic acid p-phenylphenacyl ester(112449-52-2)
• EPA Substance Registry System: (-)-α-(4-biphenylmercapto)propionic acid p-phenylphenacyl ester(112449-52-2)

Safety Data

• Hazardous Substances Data: 112449-52-2(Hazardous Substances Data)

Upstream product

• 19813-90-2 4-biphenylthiol 
• 112449-63-5 α-(4-biphenylmercapto)propionic acid 
• 135-73-9 2-Bromo-4'-phenylacetophenone 

Relevant articles and documents

EFFECT OF MOLECULAR STRUCTURE ON OPTICAL PROPERTIES OF SYSTEMS CONTAINING CHIRALITY CENTERS. PART XXXI. α-(4-BIPHENYLMERCAPTO)PROPIONIC ACIDS AND SOME OF THEIR DERIVATIVES

The synthesis and principal properties of α-(4-biphenylmercapto)propionic and α-(4-biphenylsulfonyl)propionic acids are described.A racemic mercapto acid was resolved by crystallization of its diastereomeric salts with optically active bases.The absolute configurations of enantiomers were elucidated.Optical rotatory dispersion of the laevorotatory enantiomer, its amide, and methylamide as well as its p-phenylphenacyl and p-bromophenacyl esters in the region 340 λ 600 nm was determined.Six term equations describing optical rotation of the dextrorotatory enantiomer in the spectral region studied were determined.