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DL-(1α,2β,3α,4β,5α,6β)-3,5,6-Tris(benzylthio)-1,2,4-cyclohexantriol is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

112458-48-7

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112458-48-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 112458-48-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,2,4,5 and 8 respectively; the second part has 2 digits, 4 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 112458-48:
(8*1)+(7*1)+(6*2)+(5*4)+(4*5)+(3*8)+(2*4)+(1*8)=107
107 % 10 = 7
So 112458-48-7 is a valid CAS Registry Number.

112458-48-7Relevant academic research and scientific papers

cis-/trans--Trithia- and trans--Hexathia-tris-?-homobenzenes

Kagabu, Shinzo,Kaiser, Clemens,Keller, Reinhold,Becker, Paul G.,Mueller, Klaus-Helmuth,et. al.

, p. 741 - 756 (2007/10/02)

Starting from the cis- and trans-benzene trioxides 2/7 the cis-/trans--Trithia-tris-?-homobenzenes 1/6 and the trans-dioxathia-/oxadithia analogs 19/21 are synthesized by regioselective epoxide opening reactions with appropriate S-nucleophiles.Under the influence of heat and light cis-trisulfide 1 quickly looses sulfur and does not undergo ?2+?2+?2>cycloreversion.Attempts to build up cis--tris-?-homobenzenes from 2 by threefold six-membered ring anellation, in the special case of 1,2-benzenedithiol as 1,4-dinucleophil, led preferably to the trans--hexathia-tris-?-homobenzene 44 (X-ray analysis) manifesting effective S-neighbouring group participation. cis-Trisulfide 1 is a poor tridentate ligand: only with Ni(ClO4)2 a 2:1 complex (presumably octahedral, 48) is formed.

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