112471-54-2Relevant academic research and scientific papers
Reductive addition of the benzenethiyl radical to alkynes by amine-mediated single electron transfer reaction to diphenyl disulfide
Taniguchi, Tsuyoshi,Fujii, Tatsuya,Ldota, Atsushi,Lshibashi, Hiroyuki
supporting information; experimental part, p. 3298 - 3301 (2009/12/01)
Hydrothiolation of alkynes proceeds with diphenyl disulfide and tripropylamine. Amine-mediated single electron transfer to diphenyl disulfide can be proposed for the reaction mechanism. Applications of the method to radical cyclizations of eneyne compound
Et3B Induced Radical Addition of Thiols to Acetylenes
Ichinose, Yoshifumi,Wakamatsu, Kuni,Nozaki, Kyoko,Birbaum, Jean-Luc,Oshima,Koichiro,Utimoto, Kiitiro
, p. 1647 - 1650 (2007/10/02)
Thiols added easily to acetylenic compounds in the presence of Et3B to give alkenyl sulfides in good yields.The reaction of acetylenes with 3-methyl-2-buten-1-thiol gave dihydrothiophene derivatives in one pot.
