112476-37-6

Upstream product

• 94971-86-5 benzenetellurinic acid anhydride 
• 76-05-1 trifluoroacetic acid 
• 32294-60-3 diphenyl ditelluride 
• 2712-78-9 bis-[(trifluoroacetoxy)iodo]benzene 
• 407-25-0 trifluoroacetic anhydride 

Downstream Products

• 112476-26-3 1-(ethoxycarbonyl)-2-<(phenyltelluro)methyl>pyrrolidine 
• 589-09-3 N-allyl-N-phenylamine 
• 126085-53-8 C₁₅H₂₁NO₂Te 
• 126085-49-2 C₁₄H₁₉NO₂Te 
• 118069-11-7 N-((1R,2R)-2-Phenyltellanyl-cycloheptyl)-acetamide 
• 118069-12-8 N-(1-Phenyltellanylmethyl-pentyl)-acetamide 
• 118069-10-6 N-((1R,2R)-2-Phenyltellanyl-cyclohexyl)-acetamide 
• 118069-09-3 N-((1R,2R)-2-Phenyltellanyl-cyclopentyl)-acetamide 
• 94971-86-5 benzenetellurinic acid anhydride 
• 4115-26-8 5-imino-4-phenyl-3-phenylamino-4,5-dihydro-1,2,4-thiadiazoline 
• 132413-25-3 2,2,2-Trifluoro-N-[4-phenyl-3-phenylamino-4H-[1,2,4]thiadiazol-(5Z)-ylidene]-acetamide 
• 119803-83-7 allyl pheny telluroxide 
• 112476-18-3 ethyl <1-methyl-1-phenyl-2-(phenyltelluro)ethyl>carbamate 
• 112476-20-7 ethyl <2-(phenyltelluro)cyclohexyl>carbamate 

Relevant academic research and scientific papers

Hypervalent iodine in synthesis: XVII. Actin of phenyliodine (III) dicarboxylates on diaryl ditellurides: A new and facile method for the preparation of arenetellurinic mixed anhydrides and arenetellurinic anhydrides

A new and facile method for the preparation of arenetelurinic mixed anhydrides is described from diaryl ditellurides and phenyliodine (III) dicarboxylates. Hydrolysis of the arenetellurinic mixed anhydrides gives arenetellurinic anhydrides and a one-pot p

Aminotellurinylation of Olefins and Its Utilization for Synthesis of 2-Oxazolidinones

Benzenetellurinyl acetate or trifluoroacetate in combination with ethyl carbamate effected regio- and stereoselective aminotellurinylation of olefins in the presence of boron trifluoride etherate in chloroform under reflux to give ethyl carbamates in high yields.Benzenetellurinyl trifluoromethanesulfonate similarly did it even at the lower temperature of refluxing dichloromethane without Lewis acid.This reaction was successfully extended to cyclofunctionalization of olefinic carbamates into nitrogen heterocycles.Furthermore, when the aminotellurinylation was carried out in refluxing 1,2-dichloroethane, 2-oxazolidinone was obtained in a high yield.A mechanism of addition followed by intramolecular substitution in proposed on the basis of the stereochemistry of 2-oxazolidinone derivatives.

TRANSFORMATION OF ALLYLSILANES INTO ALLYLAMINES VIA PHENYLTELLURINYLATION

Allylsilanes were treated with benzenetellurinyl trifluoracetate below room temperature followed by amines at 65 deg.C in 1,2-dichloroethane in the presence of boron trifluoride etherate, readily giving allylamines.

TELLURIUM-BASED ORGANIC SYNTHESIS: A NOVEL ONE-POT FORMATION OF 2-OXAZOLINES FROM ALKENES INDUCED BY AMIDOTELLURINYLATION

Benzenetellurinyl trifluoroacetate readily reacts with alkenes in acetonitrile in the presence of boron trifluoride etherate at 75 deg C to give 2-oxazolines via amidotellurinylation.

Aminotellurinylation of Olefins with Benzenetellurinyl Acetate and Ethyl Carbamate

Benzenetellurinyl acetate or trifluoroacetate in combination with ethyl carbamate effected aminotellurinylation of olefins in chloroform under reflux in the presence of boron trifluoride etherate to give ethyl carbamates in high yi