112497-26-4Relevant academic research and scientific papers
Hexafluoroisopropanol as a unique solvent for stereoselective lododesilylation of vinylsilanes
Ilardi, Elizabeth A.,Stivala, Craig E.,Zakarian, Armen
supporting information; experimental part, p. 1727 - 1730 (2009/04/10)
Stereoselective preparation of iodoalkenes from vinylsilanes is described. 1,1,1,3,3,3-Hexafluoroisopropanol serves as a unique solvent that ensures high yields and stereoselectivities in the iododesilylation of a variety of functionalized substrates.
Anticholinergic agents. 4. Stereocontrolled synthesis of fluorinated acetylcholine antagonists; syntheses of the two 1-cyclohexyl-1-(4-fluorophenyl)-3-piperidyl-1-propanols and their methiodides.
Sjoe,Aasen
, p. 1019 - 1024 (2007/10/02)
Four new putative muscarinic antagonists, (R)-(-)- and (S)-(+)-1-cyclohexyl-1-(4-fluorophenyl)-3-piperidyl-1-propanol and their methiodides, have been synthesised. Absolute configurations have been assigned on the basis of the anticipated chirality of the
A regiodefined synthesis of α-trimethylsilyl ketones catalyzed by rhodium(I) hydride complex
Sato, Susumu,Matsuda, Isamu,Izumi, Yusuke
, p. 71 - 88 (2007/10/02)
Regiodefined synthesis of α-trimethylsilyl ketones is attained by one of three different routes: isomerization of β-trimethylsilyl allyl alcohols (route A), isomerization of β'-trimethylsilyl allyl alcohols (route B), and dehydrogenation of β-trimethylsil
STEREOSELECTIVE SYNTHESIS OF (2E,4Z)-DIEN-1-OLS; KEY INTERMEDIATES FOR SYNTHESIS OF SEX PHEROMONES OF SILK WORM AND OF GRAPE VINE MOTH
Kuroda, Satoru,Katsuki, Tsutomu,Yamaguchi, Masaru
, p. 803 - 804 (2007/10/02)
Two (2E,4Z)-dien-1-ols, synthetic key intermediates for the insect pheromones with a (E,Z)-diene system, were synthesized stereoselectively by using a combination of zirconium-mediated Wittig rearrangement reaction and Peterson reaction as key steps.
