112503-29-4Relevant articles and documents
Reactions of N-benzyl-pyridinium or -isoquinolinium ylides with ethyl 3-fluoro-3-(fluoroalkyl)acrylates to give fluoroalkyl-substituted indolizine and pyrrolo[2,1-a]isoquinoline derivatives
Peng, Weimin,Zhu, Shizheng
, p. 3204 - 3210 (2001)
In the presence of base, N-benzylpyridinium and N-benzylisoquinolinium ylides generated in situ from the N-benzyl-pyridinium or -isoquinolinium bromides react with ethyl 3-fluoro-3-fluoroalkyl(except bromodifluoromethyl)acrylates to give one or two fluoro
Solvent reorganisation as the driving force for rate changes of Menschutkin reactions in an ionic liquid
Yau, Hon Man,Howe, Andrew G.,Hook, James M.,Croft, Anna K.,Harper, Jason B.
supporting information; experimental part, p. 3572 - 3575 (2010/01/06)
The effect on the rate of reaction of each of a series of Menschutkin processes on changing from a molecular solvent to an ionic liquid was investigated. In each case, the rate acceleration observed at room temperature could be attributed to the change in
Concurrent SN1 and SN2 reactions in the benzylation of pyridines
Yoh, Soo-Dong,Cheong, Duk-Young,Lee, Chung-Heun,Kim, Sung-Hong,Park, Jong-Hwan,Fujio, Mizue,Tsuno, Yuho
, p. 123 - 130 (2007/10/03)
The Menschutkin reactions of 3,4-methylenedioxybenzyl and 3,4-dimethoxybenzyl bromides and also p-methoxybenzyl bromide with Y-substituted pyridines were kinetically studied for a range of amine concentration in acetonitrile. The strongly activated benzyl
