112506-15-7

Basic information

• Product Name: Borinic acid, [2,4,6-tris(1,1-dimethylethyl)phenyl]-
• CAS NO: 112506-15-7
• Molecular Formula: C18H31BO
• Molecular Weight: 274.255
• Mol File: 112506-15-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Borinic acid, [2,4,6-tris(1,1-dimethylethyl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Borinic acid, [2,4,6-tris(1,1-dimethylethyl)phenyl]-(112506-15-7)
• EPA Substance Registry System: Borinic acid, [2,4,6-tris(1,1-dimethylethyl)phenyl]-(112506-15-7)

Safety Data

• Hazardous Substances Data: 112506-15-7(Hazardous Substances Data)

Upstream product

• 112506-19-1 (tetramethylethylenediamine)lithium trihydro(2,4,6-tri-tert-butylphenyl)borate 

Relevant articles and documents

Oxo(tri-tert-butylphenyl)borane ArBO as an Intermediate

The borane ArB(OMe)2 (1) (Ar = 2, 4, 6-tri-tert-butylphenyl) was transformed into ArBH3*Li(tmeda) (2) by the action of LiAlH4 in Et2O.The product 2 can be hydrolysed to ArB(OH)H (3), but in strongly acidic media the hydrolysis involves the attack of a neighbouring methyl group to give the 1-hydroxy-1-boraindane derivative 4.Borane 3 can be dehydrogenated to 4 in the gas-phase at 600 deg C.The formation of ArBO (5) as an intermediate in this dehydrogenation has been proved by starting from ArB(OD)H (3') which gives the product 4 with an OH-group in the 1-position.