112563-38-9Relevant articles and documents
Preparation and characterization of some substituted benzyl n-nitrosocarbamates containing an n-2-(methylthio)ethyl or a bis(2-aminoethyl)sulfide functionality
Venkata, Satya,Shamo, Eric,Benin, Vladimir
, p. 1406 - 1414 (2009)
The synthesis and characterization of some substituted benzyl N-nitrosocarbamates with an N-2-(methylthio)ethyl or a bis(2-aminoethyl)sulfide functionality is reported, as a part of a long-term goal to design and prepare novel photolabile structures that could be used as substances for controlled release of alkylating and/or crosslinking agents. The synthesis was accomplished by reaction of benzyl chloroformates with the corresponding amines, resulting in the preparation of carbamates. The latter were subsequently nitrosated, utilizing two different N-nitrosation methods, to yield the target structures.