112563-66-3Relevant academic research and scientific papers
SYNTHESIS OF SOME 4-ACYLOXY-7-OXO-1-AZABICYCLOHEPT-2-ENE-2-CARBOXYLATES
Bateson, John H.,Quinn, Alison M.,Southgate, Robert
, p. 1561 - 1564 (2007/10/02)
Allylic oxidation of 4-allyl-1-dimethyl-t-butylsilylazetidin-2-ones (5,7) gave the 4-(1-hydroxyprop-2-ene-1-yl) derivatives (6,8).Radical benzoyloxylation of the silylated 8-oxo-7-azabicyclooct-3-ene (18) provided four allylic monobenzoates.Progression of (8) and (29) afforded, respectively, 4-acyloxy olivanic acid analogues containing trans- (16) and cis- (31) substituents at C-6.
