1125854-75-2Relevant academic research and scientific papers
A new insight into the catalytic decomposition of ethyl diazoacetate in the presence of meso-tetraarylporphyrin (=5,10,15,20-tetraaryl-21H,23H-porphine) complexes
Gomes, Ana T. P. C.,Leao, Raquel A. C.,Alonso, Cristina M. A.,Neves, Maria G. P. M. S.,Faustino, Maria A. F.,Tome, Augusto C.,Silva, Artur M. S.,Pinheiro, Sergio,De Souza, Maria Cecilia B. V.,Ferreira, Vitor F.,Cavaleiro, Jose A. S.
, p. 2270 - 2283 (2009/03/12)
The decomposition of ethyl diazoacetate by several catalysts in the presence of meso-tetraarylporphyrin complexes with different electronic features was evaluated. The distribution of the obtained products (chlorins, bacteriochlorins, isobacteriochlorins, and porphyrin derivatives resulting from C-H insertion and Buechner ring expansion) is dependent on the catalyst and on the electronic features of the meso-aryl groups.
