112586-92-2

Upstream product

• 762-73-2 trimethyl(allyl)stannane 
• 112587-05-0 1-nitro-6-phenylhexa-1,5-diene 
• 121948-52-5 (E,E)-6-phenyl-1-nitrohexa-1,5-diene 
• 121948-43-4 1-nitro-6-phenylhex-5-en-2-ol 
• 36884-75-0 (E)-5-phenylpent-4-enal 
• 122045-13-0 2-Allyl-5-(chloro-phenyl-methyl)-cyclopentanone oxime 

Relevant academic research and scientific papers

Stepwise Intramolecular Cycloaddition of Nitrile Oxide Equivalents Derived from the Lewis Acid-promoted Reaction of 1-Nitroalkadienes and Allylic Stannanes

The Lewis acid-promoted reaction of 1-nitroalka-1,5-(or 1,6-)dienes with allylic stannanes has been studied.In the presence of TiCl4, 1-nitrohexa-1,5-diene reacted smoothly with allyltrimethylstannane to give a diastereoisomeric mixture of 6-allyl-3a,4,5,

A Novel Synthesis of Bicyclic Isoxazolines via Sequential Michael and Intramolecular 1,3-Dipolar Additions

Bicyclic isoxazolines are obtained in good yields by the titanium tetrachloride-mediated reaction of allylic stannanes with 1-nitroalkadienes.Titanium tetrachloride converts stannyl nitronates generated in the Michael addition step to nitrile oxide equiva