112608-06-7

Upstream product

• 112608-04-5 (2S,3S)-4-Benzyloxy-2,3-bis-methoxymethoxy-1-(4-methoxy-phenyl)-butan-1-one oxime 

Downstream Products

• 108082-49-1 (2S,3S,4S,5S)-3,4-bis<(methoxymethyl)oxy>-2-(p-methoxyphenyl)-1,5-dimethylpyrrolidine 
• 112722-07-3 4-Nitro-benzoic acid (2S,3S,4S)-4-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)-2,3-dihydroxy-4-(4-methoxy-phenyl)-butyl ester 
• 99945-49-0 (1S,2S,3S)-4-(benzyloxy)-2,3-bis<(methoxymethyl)oxy>-1-(p-methoxyphenyl)-1-(1,3-dioxo-2-azindan-2-yl)butane 

Relevant academic research and scientific papers

STEREOCHEMICAL REVISION AND ABSOLUTE CONFIGURATION OF CODONOPSININE

The stereostructure of codonopsinine has been revised from 1 to 7 based on chemical correlation studies, NOE expereriments, and X-ray crystallographic analysis.This establishes the absolute configuration of natural (-)-codonopsinine as 2R, 3R, 4R, 5R.

anti Selectivity in α-Chelation Controlled Hydride Addition to Acyclic Alkoxy Ketone Oximes: Preparation of Chiral Primary anti Amines

Hydride addition to acyclic α-alkoxy and α,β-dialkoxy ketone oximes using aluminium hydride reagents proceeds in an anti-selective manner under α-chelation control, providing chiral anti amines.