112610-22-7Relevant academic research and scientific papers
ISOMERAZATION OF PROPARGYLIC ALCOHOLS CATALYZED BY AN IRIDIUM COMPLEX
Ma, Dawei,Lu, Xiyan
, p. 2109 - 2112 (1989)
α,β-Enones were synthesized by the isomerization of propargylic alcohols catalyzed by an iridium pentahydride complex.
Reinvestigation on the Catalytic Isomerisation of Carbon-Carbon Triple Bonds
Guo, Cheng,Lu, Xiyan
, p. 1921 - 1924 (2007/10/02)
Based on the discovery that phosphines could catalyse the isomerisation of triple bonds, the isomerisation of acetylenic derivatives was differentiated into two types: phosphine-catalysed and transition metal-catalysed.
Isomerization of alkynemono-ols catalyzed by palladium(0) complex and diols
Lu, Xiyan,Ji, Jianguo,Guo, Cheng,Shen, Wei
, p. 259 - 266 (2007/10/02)
Isomerization of alkynemono-ols occurred by the catalysis of Pd2(dba)3 * CHCl3 (1) + iPr3P + HOCH2CH2OH.Palladium hydride active species were supposed to be formed in situ by the oxidative addition of diols to 1 as determined bu 1H NMR spectra.
