1126519-23-0Relevant academic research and scientific papers
Catalytic asymmetric cross-couplings of racemic α-bromoketones with arylzinc reagents
Lundin, Pamela M.,Esquivias, Jorge,Fu, Gregory C.
supporting information; experimental part, p. 154 - 156 (2009/04/07)
(Chemical Equation Presented) Nickel box: The first catalytic asymmetric method for cross-coupling arylzinc reagents with α-bromoketones has been developed (see scheme). This stereoconvergent carbon-carbon bond-forming process occurs under unusually mild conditions and without activators, thereby allowing the generation of potentially labile tertiary stereocenters.
