112712-93-3

Upstream product

• 12080-32-9 dichloro(1,5-cyclooctadiene)platinum(ll) 
• 22031-12-5 [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] 
• 13869-38-0 bis(acetonitrile)dichloroplatinum(II) 

Downstream Products

• 112712-96-6 {platinum⁽⁰⁾(tripod)(P(3,5-(CF₃)2C₆H₃)3)} 
• 167102-07-0 PtBr₂(1,1,1-tris(diphenylphosphinomethyl)ethane) 
• 167102-06-9 [Pt(CN)2(1,1,1-tris(diphenylphosphinomethyl)ethane)] 
• 196500-69-3 PtH₃(CH₃C(CH₂P(C₆H₅)2)3)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[PtH₃(CH₃C(CH₂P(C₆H₅)2)3)]B(C₆H₅)4 
• 134494-07-8 {Pt(1,1,1-tris(diphenylphosphinomethyl)ethane)(SPh)2} 

Relevant academic research and scientific papers

The synthesis of palladium-gold and platinum-gold bimetallic complexes based upon tripod tridentate phosphine and arsine ligands

The planar complexes MLCl2 [M = Pd or Pt; L = MeC(CH2PPh2)3, MeC (CH2AsPh2)3, MeC(CH2AsMe2)3, MeC(CH2SMe)3 or MeC(CH2

Synthesis and Dynamic Stereochemistry of the Complexes (SR)(H)> (R = H or Ph)

The cis square-planar hydrido mercapto derivatives and have been prepared by reaction of with H2S or HSPh.Analysis of the 1H and 31P NMR data for the two complexes over a temperature range encompassing slow- and fast-exchange limits characterizes these molecules as stereochemically nonrigid on the NMR time-scale.The fluxional behaviour can be explained on the basis of intramolecular exchange of the unco-ordinated phosphorus atom of triphos with the phosphorus atom co-ordinated in cis position to the hydride ligand.At higher temperature, a complete scrambling of the three phosphorus atoms occurs, and at the fast-exchange limit the spin correlation between the phosphorus atoms and platinum metal is retained.The related complexes (dppp = Ph2PCH2CH2CH2PPh2), and have been prepared in order to clarify the mechanism of the fluxionality for (R = H or Ph).