1127306-95-9Relevant academic research and scientific papers
A ring closing metathesis-manganese dioxide oxidation sequence for the synthesis of substituted pyrroles
Keeley, Aaron,McCauley, Shane,Evans, Paul
, p. 2552 - 2559 (2016)
The combination of ring closing, or enyne metathesis with oxidation in order to prepare N-sulfonyl pyrroles is described. Reasonable to good yields were obtained for a variety of substituents and the procedure may also be conducted in one-pot. 2-Bromo N-sulfonyl adducts prepared in this manner were subjected to an intramolecular Heck-type cyclisation, forming cyclic sulfonamides.
