112798-27-3Relevant academic research and scientific papers
Stereochemical Studies. Part 102/106: Saturated Heterocycles; Preparation of Saturated Methylene-Bridged 2-Arylimino-1,3-benzoxazines
Stajer, G.,Szabo, A. E.,Bernath, G.,Sohar, P.
, p. 448 - 449 (2007/10/02)
Thioureas 3a-c from 3-exo-aminomethylbicycloheptan-2-exo-ol (1) and aryl isothiocyanates 2a-c were cyclized to tricyclic arylimino-1,3-oxazines 4a-c.The ringclosure of 3a-c to the analogoues 1,3-thiazines is unfavoured for steric reasons.
