112799-31-2

Basic information

• Product Name: 1H-Pyrrole-3-carboxylic acid, 4-[[2-(methoxycarbonyl)phenyl]thio]-2-methyl-1-(phenylmethyl)-, methyl ester
• CAS NO: 112799-31-2
• Molecular Formula: C22H21NO4S
• Molecular Weight: 395.479
• Mol File: 112799-31-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1H-Pyrrole-3-carboxylic acid, 4-[[2-(methoxycarbonyl)phenyl]thio]-2-methyl-1-(phenylmethyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Pyrrole-3-carboxylic acid, 4-[[2-(methoxycarbonyl)phenyl]thio]-2-methyl-1-(phenylmethyl)-, methyl ester(112799-31-2)
• EPA Substance Registry System: 1H-Pyrrole-3-carboxylic acid, 4-[[2-(methoxycarbonyl)phenyl]thio]-2-methyl-1-(phenylmethyl)-, methyl ester(112799-31-2)

Safety Data

• Hazardous Substances Data: 112799-31-2(Hazardous Substances Data)

Upstream product

• 7039-93-2 2,5-Dihydrofuran-2,5-dimethoxy-2-methylfuran-3-carbonsaeuremethylester 
• 6141-58-8 methyl 2-methyl-3-furancarboxylate 
• 4892-02-8 Methyl thiosalicylate 
• 112799-44-7 Tetrahydro-2,5-dimethoxy-4-(2-methoxycarbonylphenylthio)-2-methylfuran-3-carbonsaeuremethylester 
• 100-46-9 benzylamine 

Relevant articles and documents

4-(Phenylthio)-pyrrole-3-carboxylic Acid Esters

Dihydro(dimethoxy)methylfurancarboxylic acid esters 4A/4B have been applied to the synthesis of the title compounds.With amines as catalysts they react with thiophenols to give the addition products 12a-d, which upon heating with acids eliminate methanol to form the furancarboxylic acid esters 13a-b and 17, whereas reactions with ammonia or amines lead to the pyrrolecarboxylic acid esters 20a-e.Reactions of 4 with 2-aminothiophenol yield the fused pyrrole and pyrrolidine derivatives 15 and 16.Compounds 20b and e were transformed to the benzothiopyranopyrrole carboxylic acid esters 23a and b.