1128080-16-9Relevant academic research and scientific papers
Efficient synthesis of 13C-labelled erythromycin biosynthetic intermediate. 1: S-2-acetylaminoethyl (2R,3R,4R,5R)-3,5-diacetoxy-2,4-dimethyl- 4-([13C]methoxy)-heptanethioate
Iida, Katsumi,Kajiwara, Masahiro,Inoue-Tanihata, Tomoko,Fukui, Mineo,Nakata, Tadashi,Oishi, Takeshi
, p. 213 - 217 (2008/12/20)
An efficient 13C-labelling synthesis of the putative erythromycin biosynthetic intermediate, S-2-acetylaminoethyl (2R,3R,4R,5R)-3,5-diacetoxy-2,4-dimethyl-4-([13C]methoxy) heptanethioate, which would be useful for the investigation of the chain elongation mechanism in erythromycin biosynthesis, was achieved by utilizing iodo[13C]methane and (2S,3R,4R,5R)-4-hydroxy-3,5-O-isopropylidene-2, 4-dimethylheptanol, obtained in our previous studies on erythromycin A synthesis. Copyright
