1128085-88-0Relevant academic research and scientific papers
In situ preparation of rhodium/N-heterocyclic carbene complexes and use for addition of arylboronic acids to aldehydes
Kilincarslan, Rafet,Yigit, Murat,Oezdemir, Ismail,Cetinkaya, Engin,Cetinkaya, Bekir
, p. 69 - 73 (2007)
(Chemical Equation Presented) The in situ prepared three component system [RhCl(COD)]2/imidazolidinium salts (2, 4) and KOBut catalyses the addition of phenylboronic acid to sterically hindered aldehydes affording the corresponding arylated secondary alcohols in good yields. Four novel 1,3-dialkylimidazolidinium (2-4) salts as NHC precursors were synthesized from N,N′-dialkylethylenediamine.
