112818-20-9Relevant academic research and scientific papers
Environmentally friendly TPDS-mediated free radical ring expansion of α-haloalkyl cyclic β-keto esters
Sugi, Masaaki,Togo, Hideo
, p. 3171 - 3175 (2002)
Reactivities of tetraphenyldisilane (TPDS), tris(trimethylsilyl)silane, and tributyltin hydride in the radical ring expansion of α-haloalkyl cyclic β-keto esters were examined. Among these reagents, TPDS was found most effective for the preparation of medium-sized cyclic compounds in terms of yields and ring-expansion/reduction selectivity.
