112835-91-3 Usage
General Description
2(1H)-Pentalenone, 5-acetyl-3,3a,4,6a-tetrahydro-, (3aS)- (9CI) is a chemical substance also known as 5-Acetyl-2(1H)-pentalenone, with the molecular formula C13H14O2. It is a yellowish-brown liquid with a camphor-like odor and is primarily used as an intermediate in the production of pharmaceuticals and other organic compounds. This chemical has potential applications in the field of organic synthesis and medicinal chemistry. Its unique structure and properties make it a valuable component in the development of various pharmaceutical products and research in the area of organic chemistry.
Check Digit Verification of cas no
The CAS Registry Mumber 112835-91-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,2,8,3 and 5 respectively; the second part has 2 digits, 9 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 112835-91:
(8*1)+(7*1)+(6*2)+(5*8)+(4*3)+(3*5)+(2*9)+(1*1)=113
113 % 10 = 3
So 112835-91-3 is a valid CAS Registry Number.
112835-91-3Relevant articles and documents
APPLICATION OF MICROORGANISMS AND ENZYMES TO THE SYNTHESIS OF CHIRAL CYCLOPENTANE AND BICYCLOOCTANE DERIVATIVES
Xie, Zhuo-Feng,Suemune, Hiroshi,Nakamura, Izumi,Sakai, Kiyoshi
, p. 4454 - 4459 (2007/10/02)
Optically active cyclopentane and bicyclooctane derivatives were synthesized by utilizing biochemical methods.Pseudomonas fluorescens lipase was found to be an effective enzyme for the enantioselective hydrolysis of monoacetoxy- and diacetoxycyclopentanes such as (+/-)-4a, (+/-)-5a, (+/-)-6a, and 7a.However,hydrolysis of bicyclooctane trans-acetate ((+/-)-8a) using this enzyme resulted low enantioselectivity.Optically pure (+)-8b for the synthesis of carbacyclin was obtained from (+/-)-8a by using porcine pancreatic lipase.Reduction of 3-acetyl-7-oxobicyclo-oct-2-ene with baker's yeast afforded a useful intermediate((+)-11b) for the synthesis of hirsutic acid.Keywords - enzymatic hydrolysis; enantioselective hydrolysis; bicyclo-octane; baker's yeast; carbacyclin; hirsutic acid