112861-35-5Relevant academic research and scientific papers
PREPARATION AND REACTIVITY OF THR PENTAMETHYLCYCLOPENTADIENYL COMPLEXES 5-C6Me5)Ru(PPh3)(L)Cl> (L=CO, ButNC) AND 5-C5Me5)Ru(L)2Cl> (L=ButNC, norbornadiene)
Conroy-Lewis, Fiona M.,Simpson, Stephen J.
, p. 221 - 228 (2007/10/02)
The chloro complexes 5-C5Me5)Ru(norbornadiene)Cl> (2), 5-C5Me5)Ru-(ButNC)2Cl> (3), 5-C5Me5)Ru-(PPh3)(ButNC)Cl> (4) and 5-C5Me5)Ru(PPh3)-(CO)Cl> (5) have been prepared from 5-C5Me5)Ru(PPh3)2Cl (1).Reaction of 3-5 with sodium methoxide gave the corresponding hydrides 7-9.All the chloro complexes 1-5 ionise readily in methanol containing NH4PF6 and a donor ligand to give a range of new cations as hexafluorophosphate salts.Treatment of 1 and 4 with NOBF4 gave the dicationic nitrosyls, 5-C5Me5)Ru(PPh3)2NO>(BF4)2 (12) and 5-C5Me5)Ru(PPh3)ButNC)NO>(BF4)2 (17), respectively.
