112882-07-2Relevant academic research and scientific papers
Sterically Crowded Sulfonate Esters: Novel Leaving Groups with Hindered S-O Cleavage
Netscher, Thomas,Prinzbach, Horst
, p. 683 - 688 (1987)
Reagents and procedures for the preparation of tert-butyl sulfonate esters 2 and 2,2,2-trifluoro-1,1-diphenylethane sulfonate esters 3 (TDE-sulfonates) are described.In these new sulfonates, S-O-scission is reduced significantly by steric hindrance.
