112896-48-7Relevant academic research and scientific papers
Detection and Decomposition of Di-tert-butyl Disulfide - Polyoxide Derivatives
Derbesy, Gerard,Harpp, David N.
, p. 1044 - 1052 (1995)
The chemistry of di-tert-butyl disulfide polyoxide derivatives has been investigated.Low-temperature experiments permit the clear detection of vic-disulfoxides (α-disulfoxides).In addition, a proposal for a decomposition mechanism that accounts for the detection of one of the diastereoisomers and the formation of the final products has been advanced.The formation of di-tert-butyl thiosufonate was also shown to be solvent and concentration dependent.Finally, low-temperature experiments permit the detection of the sulfinyl sulfone and vic-disulfone derivatives.A general mechanism has been proposed for the decomposition of these disulfide polyoxide derivatives.
Peroxidation of S-(2-Methyl-2-propyl) 2-Methyl-2-propanesulfinothioate
Freeman, Fillmore,Lee, Choonsun
, p. 1263 - 1266 (2007/10/02)
Oxidation of 1 equiv of S-(2-methyl-2-propyl) 2-methyl-2-propanesulfinothioate (1) with 2 equiv of m-chloroperoxybenzoic acid (MCPBA) gives S-(2-methyl-2-propyl) 2-methyl-2-propanesulfonothioate (4, 13percent), 2-methyl-2-propanesulfenic 2-methyl-2-propanesolfonic thioanhydride (5, 32percent), 2-methyl-2-propyl-3-chlorobenzoate (11, 4percent), 2-methyl-2-propyl 2-methyl-2-propanesulfinate (12, 22percent), and small amounts of bis(2-methyl-2-propyl) trisulfide (7) and bis(2-methyl-2-propyl) tetrasulfide (10).Possible mechanisms for product formation are discussed.
