112897-06-0

Basic information

• Product Name: (2R,3R)-1-(tert-butyldiphenylsilyloxy)-2-methylhex-5-en-3-ol
• Synonyms: (2R,3R)-1-(tert-butyldiphenylsilyloxy)-2-methylhex-5-en-3-ol
• CAS NO: 112897-06-0
• Molecular Weight: 368.591
• Mol File: 112897-06-0.mol

Chemical Properties

• CAS DataBase Reference: (2R,3R)-1-(tert-butyldiphenylsilyloxy)-2-methylhex-5-en-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3R)-1-(tert-butyldiphenylsilyloxy)-2-methylhex-5-en-3-ol(112897-06-0)
• EPA Substance Registry System: (2R,3R)-1-(tert-butyldiphenylsilyloxy)-2-methylhex-5-en-3-ol(112897-06-0)

Safety Data

• Hazardous Substances Data: 112897-06-0(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 106356-53-0 B-allyldiisopinocampheylborane 
• 91751-24-5 (R)-3-[(tert-butyldiphenylsilyl)oxy]-2-methylpropanal 
• 24850-33-7 allyltributylstanane 

Downstream Products

• 1352286-67-9 (R)-6-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-3-methyl-5,6-dihydro-2H-pyran-2-one 
• 1352286-66-8 (2R,3R)-1-(tert-butyldiphenylsilyloxy)-2-methylhex-5-en-3-yl methacrylate 
• 146070-52-2 (E)-(R)-5-(tert-Butyl-dimethyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxy)-6-methyl-hept-2-enoic acid ethyl ester 
• 146070-50-0 2-[(R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(tert-butyl-diphenyl-silanyloxy)-5-methyl-hexyl]-[1,3]dithiane 
• 146070-48-6 (R)-5-(tert-Butyl-dimethyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxy)-6-methyl-heptanal 

Relevant articles and documents

Stereoselective total synthesis of arenastatin A, a spongean cytotoxic depsipeptide

A highly stereoselective total synthesis of arenastatin A, an extremely potent cytotoxic cyclic depsipeptide from marine sponge, was developed. The desired 7,8-β-epoxide in arenastatin A was constructed by asymmetric sulfur ylide-mediated epoxidation in g

Iridium-catalyzed allylation of chiral β-stereogenic alcohols: Bypassing discrete formation of epimerizable aldehydes

The cyclometalated π-allyliridium 3,4-dinitro-C,O-benzoate complex modified by (R)- or (S)-Cl,MeO-BIPHEP promotes the transfer hydrogenative coupling of allyl acetate to β-stereogenic alcohols with good to excellent levels of catalyst-directed diastereose

Two Routes to Chiral Dithianes, Useful Synthons for the Preparation of Functionalised Spiroketals

Two routes are described leading to chiral precursors for the synthesis of new substituted spiroketals.The stabilities of the methoxymethyl, tert-butyldimethylsilyl and tert-butyldiphenylsilyl hydroxyl protecting groups were tested in these reaction seque