112933-55-8Relevant academic research and scientific papers
B(C6F5)3-catalyzed hydrogenation of oxime ethers without cleavage of the N-O bond
Mohr, Jens,Oestreich, Martin
supporting information, p. 13278 - 13281 (2015/01/16)
The hydrogenation of oximes and oxime ethers is usually hampered by N-O bond cleavage, hence affording amines rather than hydroxylamines. The boron Lewis acid B(C6F5)3 is found to catalyze the chemoselective hydrogenation
A convenient method for the synthesis of O-tert-butyldimethylsilyl oximes
Ortiz,Cordero,Pinto,Alverio
, p. 409 - 415 (2007/10/02)
Aromatic, aliphatic, cyclic and acyclic O-tert-butyldimethylsilyl oximes were prepared in 77 to 85% yield by the reaction of the corresponding aldoximes and ketoximes with tert-butyldimethylchlorosilane (TBSCI) using imidazole/DMF system.
