1129673-93-3

Upstream product

• 131276-28-3 1,8-bis(diphenylphosphino)-9-anthrylpalladium(II) chloride 
• 762-42-5 dimethyl acetylenedicarboxylate 

Downstream Products

• 1356934-82-1 [C₁₆H₇(PPh₂)2(COOMe)2]Pd(acetonitrile) tetrafluoroborate 

Relevant academic research and scientific papers

SYNTHESIS OF STABLE C-(sup3)-CARBOMETALATED TRANSITION METAL COMPLEXES

The present invention provides a novel process for preparing carbometalated transition metal complexes, by reacting a transition metal complex having at least one conjugated diene ligand, with a dienophile, in a Diels-Alder cycloaddition reaction. In a particular embodiment, the invention discloses turning anthracene-based 9-C(sp2)-metalated complexes into C(sp3)-metalated ones by organic synthesis involving the Diels-Alder reaction.

Diels-Alder cycloaddition as a new approach toward stable PC(sp 3)P-metalated compounds

A straightforward synthetic route toward a new family of dibenzobarrelene-based cyclometalated compounds is described. The Royal Society of Chemistry.