1129711-37-0Relevant articles and documents
Light-sensitive and recoverable n-heterocyclic carbene copper(I) complex in homogeneous catalysis
Zhang, Guodong,Lang, Rui,Wang, Wenlong,Lv, Hui,Zhao, Liyuan,Xia, Chungu,Li, Fuwei
supporting information, p. 917 - 922 (2015/03/30)
The synthesis of a light-responsive N-heterocyclic carbene copper(I) complex by introducing a nitrobenzospiropyran unit into the carbene ligand was developed. The solubility of this complex was controlled through reversible conversion between its netural and ionic states using ultraviolet light irradiation. Taking advantage of such a light-sensitive property facilitated its recovery and reuse in copper(I)-catalyzed homogeneous oxidation and "click" reactions.
Fluorophore tagged cross-coupling catalysts
Sashuk, Volodymyr,Schoeps, Dirk,Plenio, Herbert
supporting information; experimental part, p. 770 - 772 (2009/07/10)
Fluorophore tagged N-heterocyclic carbenes and the derived (NHC)Pd(allyl)Cl complexes were synthesized and the fluorescence signal was used to follow the course of a Suzuki coupling reaction. The Royal Society of Chemistry.