112978-57-1Relevant academic research and scientific papers
C-CENTRED OPTICALLY ACTIVE ORGANOSILANES,1. SYNTHESIS OF NEW SILYLATED CHIRAL AUXILIARIES.
Coppi, Laura,Ricci, Alfredo,Taddei, Maurizio
, p. 965 - 968 (2007/10/02)
Different silylating reagents with an optically active ligand bonded to the silicon centre have been synthesized starting from (1R)(-)myrtenal.The key step of the synthesis is the stereocontrolled 1,4 addition of phenyldimethylsilyl-cuprate to the α,β unsaturated aldehyde.
