112980-52-6Relevant academic research and scientific papers
Selectivity guidelines and a reductive elimination-based model for predicting the stereochemical course of conjugate addition reactions of organocuprates to γ-alkoxy-α,β-enoates
Kireev, Artem S.,Manpadi, Madhuri,Kornienko, Alexander
, p. 2630 - 2640 (2007/10/03)
Current models used to predict the stereochemical outcome of organocopper conjugate addition processes focus on the nucleophilic addition step as stereochemistry-determining. Recent kinetic, NMR, kinetic isotope effect, and theoretical density functional
INTRAMOLECULAR NITRILE OXIDE CYCLOADDITION ON CHIRAL OLEFINS : A STEREOCONTROLLED APPROACH TO β-KETOL PRECURSORS.
Annunziata, Rita,Cinquini, Mauro,Cozzi, Franco,Dondio, Gulio,Raimondi, Laura
, p. 2369 - 2380 (2007/10/02)
The intramolecular nitrile oxide cycloaddition reaction on (E) or (Z) olefins featuring a sulphur atom along the carbon chain connecting dipole and dipolarophile occurs with a poor to excellent anti stereoselectivity, which is mainly affected by the subst
