112988-09-7

Basic information

• Product Name: (Mn(C₅H₄NCO₂)2)2((OC₆H₄CHNCH₂)2C₆H₄)
• Synonyms: (Mn(C₅H₄NCO₂)2)2((OC₆H₄CHNCH₂)2C₆H₄)
• CAS NO: 112988-09-7
• Molecular Weight: 940.686
• Mol File: 112988-09-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Mn(C₅H₄NCO₂)2)2((OC₆H₄CHNCH₂)2C₆H₄)(CAS DataBase Reference)
• NIST Chemistry Reference: (Mn(C₅H₄NCO₂)2)2((OC₆H₄CHNCH₂)2C₆H₄)(112988-09-7)
• EPA Substance Registry System: (Mn(C₅H₄NCO₂)2)2((OC₆H₄CHNCH₂)2C₆H₄)(112988-09-7)

Safety Data

• Hazardous Substances Data: 112988-09-7(Hazardous Substances Data)

Upstream product

• 79257-38-8 (Mn(C₅H₄NCO₂)2(CH₃COCHCOCH₃)) 
• 51540-97-7 2,2'-(1,3-phenylenebis(methylene))bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)diphenol 

Relevant articles and documents

Synthesis and characterization of binuclear manganese complexes: Redox models for the water oxidation cofactor of photosystem II

Binuclear manganese complexes have been prepared (a) via the use of bridging quadradentate bis(Schiff bases) and dipicolinates and (b) with bis(μ-oxo) groups and one or two picolinate ligands per manganese. Their redox chemistry, which has been characterized by cyclic voltammetry and controlled-potential coulometry, indicates that the electron-transfer mechanisms are ligand-centered rather than metal-centered. Several of the complexes appear to be effective reaction mimics and models for the manganese cofactor in photosystem II that facilitates water oxidation to dioxygen.