1130-89-8Relevant articles and documents
Facile, regioselective oxidative selenocyanation of: N -aryl enaminones under transition-metal-free conditions
Sorabad, Ganesh Shivayogappa,Maddani, Mahagundappa Rachappa
, p. 2222 - 2227 (2020)
A direct and straightforward approach for the regioselective selenocyanation of N-aryl enaminones through sp2 C-H functionalization has been realized at room temperature. In this study, KSeCN as the selenocyanate reagent and K2S2O8 as the oxidizing agent are employed under transition-metal-free conditions. The present methodology was also applied for the synthesis of selenocyanated chromones, indoles and anilines in good to excellent yields.
Triselenium dicyanide from malononitrile and selenium dioxide. One-pot synthesis of selenocyanates
Kachanov, Andrey V.,Slabko, Oleg Yu.,Baranova, Olga V.,Shilova, Evgenia V.,Kaminskii, Vladimir A.
, p. 4461 - 4463 (2007/10/03)
Triselenium dicyanide is formed by the interaction of malononitrile and selenium dioxide in dimethylsulfoxide or dimethylformamide. Addition of aromatic amines, indoles and some active methylene compounds to this reaction mixture gives the corresponding s
