113003-27-3Relevant academic research and scientific papers
Ethyl Cyanoformate/Hydrogen Peroxide and Related Combination Systems, Novel Epoxidizing Systems of Olefins
Masaki, Yukio,Miura, Tsuyoshi,Mukai, Isao,Itoh, Akichika,Oda, Hirohisa
, p. 1937 - 1940 (2007/10/02)
A combination system of ethyl cyanoformate and hydrogen peroxide was found to epoxidize olefins in a stereospecific manner at room temperature.Asymmetric epoxidation was observed with menthyl cyanoformate/hydrogen peroxide system.
BIOMIMETIC EPOXIDATION OF BIOLOGICALLY SIGNIFICANT NONCONJUGATED DIOLEFINS
Nali, Micaela,Rindone, Bruno,Tollari, Stefano,Valletta, Lorenzo
, p. 207 - 212 (2007/10/02)
Neryl ethers and geranyl ethers are regioselectively oxidised by tetraphenylporphyrinato manganese(III) acetate/NaClO under phase-transfer conditions in pH 7 buffer to give monoepoxides at the isopropylidene double bond.Also chlorinated products are formed.The subsequent epoxidation at the allylic double bond is less efficient than the electrophilic with a neryl ether, more efficient with a geranyl ether.Chlorination may be suppressed by adding pyridine to the reaction medium.This leads to a faster reaction.
