1130784-80-3 Usage
Reaction
Catalyst used in the hydrocarboxylation of terminal alkenes in supercritical carbon dioxide.
Palladium catalyst used for the direct arylation of heteroarenes.
Catalyst used in a nonoxidative cyclization reaction.
Air and thermostable catalyst used for Suzuki coupling reactions.
Uses
Tris{tris[3,5-bis(trifluoromethyl)phenyl]phosphine}palladium is used as a catalyst in coupling reactions for example, Suzuki.
Check Digit Verification of cas no
The CAS Registry Mumber 1130784-80-3 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,1,3,0,7,8 and 4 respectively; the second part has 2 digits, 8 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 1130784-80:
(9*1)+(8*1)+(7*3)+(6*0)+(5*7)+(4*8)+(3*4)+(2*8)+(1*0)=133
133 % 10 = 3
So 1130784-80-3 is a valid CAS Registry Number.
1130784-80-3Relevant articles and documents
Superstable palladium(0) complex as an air-and thermostable catalyst for Suzuki coupling reactions
Jakab, Alexandra,Dalicsek, Zoltn,Holczbauer, Tams,Hamza, Andrea,Ppai, Imre,Finta, Zoltn,Timri, Gza,Sos, Tibor
supporting information, p. 60 - 66 (2015/02/02)
An unprecedentedly thermo-and air-stable Pd0 complex from readily available electron-poor trifluoromethylated phosphine was serendipitously discovered. As detailed and comparative DFT calculations indicate, the stability of the complex is associated with unusually strong ligand-ligand noncovalent interactions. The unique stability and the presence of hydrophobic structural elements of the complex offer several practical advantages, which were exploited in catalytic Suzuki-Miyaura coupling reactions.
