1131-29-9Relevant academic research and scientific papers
Alkyl Nitrenes from N-Alkylbenzoquinone Imine N-Oxides
Baldry, Peter J.,Forrester, Alexander R.,Ogilvy, Munro M.,Thomson, Ronald H.
, p. 2027 - 2034 (2007/10/02)
Alkyl nitrenes have been generated by photolysis of two N-t-alkylbenzoquinone imine N-oxides.These mainly abstract hydrogen to give the corresponding amines which are trapped by reaction with benzoquinone.Intramolecular hydrogen abstraction followed by cyclisation to give a pyrrolidine is a minor process in one case.Attempts to generate α-substituted benzyl nitrenes in this way led mainly to the production of substituted benzyl radicals by C-N bond cleavage of the N-benzylbenzoquinone imine N-oxides.
Nitroxide Radicals. Part 20. Formation and Reactions of t-Butyl p-Formylphenyl Nitroxide and its Derivatives
Forrester, Alexander R.,Henderson, John,Hepburn, Stuart P.
, p. 1165 - 1172 (2007/10/02)
Preparation of the parent hydroxylamine of the title nitroxide and its conversion into several hydroxylamine derivatives and the corresponding nitroxides has been achieved with a view to using functionalised aryl nitroxides as spin labels.The aN/sub
