113161-99-2

Basic information

• Product Name: Ru(CO)Cl(S₂CHCCHC(CH₃)3)(P(C₆H₅)3)2
• CAS NO: 113161-99-2
• Molecular Weight: 848.411
• Mol File: 113161-99-2.mol

Chemical Properties

• CAS DataBase Reference: Ru(CO)Cl(S₂CHCCHC(CH₃)3)(P(C₆H₅)3)2(CAS DataBase Reference)
• NIST Chemistry Reference: Ru(CO)Cl(S₂CHCCHC(CH₃)3)(P(C₆H₅)3)2(113161-99-2)
• EPA Substance Registry System: Ru(CO)Cl(S₂CHCCHC(CH₃)3)(P(C₆H₅)3)2(113161-99-2)

Safety Data

• Hazardous Substances Data: 113161-99-2(Hazardous Substances Data)

Upstream product

• 113161-97-0 Ru(CO)Cl(HCCH-t-Bu)(PPh₃)2 

Relevant articles and documents

The formation of alkenedithiocarboxylate and alkenecarboxylate ligands by insertion of CS2 and CO2 into ruthenium(II)-alkenyl bonds

The unsaturated alkenyl complexes Ru(CO)Cl(RC=CHR')(PPh3)2 react with CS2 and CO2 to give Ru(CO)Cl(S2CRC=CHR')(PPh3)2 and Ru(CO)Cl(O2CRC=CHR')(PPh3)2 complexes, respectively.The products are hexacoordinated-ruthenium(II) complexes containing alkenedithioc

Insertion of carbon disulfide into ruthenium-alkenyl bonds. Formation of an alkenedithiocarboxylate ligand

CS2 reacts with complexes Ru(CO)Cl(HC= CHR)(PPh3)2 (R = Ph or t-Bu) to give products Ru(CO)-Cl(S2C(H)C=CHR)(PPh3)2 (R = Ph (1) and t-Bu (2)). The insertion products contain an alkenedithioc