1132641-71-4Relevant academic research and scientific papers
Regio- and stereoselective hydrosilylation of immobilized terminal alkynes
Pedersen, Palle J.,Henriksen, Jonas,Gotfredsen, Charlotte H.,Clausen, Mads H.
, p. 6220 - 6223 (2008)
Regio- and stereoselective hydrosilylation of terminal alkynes on solid support using diisopropyl hydrosilanes yielding β-(E)-vinyl silanes with excellent selectivity is reported. The hydrosilylation is catalyzed by Pt(DVDS)/P(iBuNCH2CH2)3N (DVDS = 1,3-divinyl-1,1,3,3-tetramethyl-disiloxane), in which the bulky proazaphosphatrane ligand plays a key role for the selectivity. The immobilized products are characterized with gel phase 13C NMR and 1H high resolution magic angle spinning NMR.
