113273-88-4

Basic information

• Product Name: 4-tert-Butylcarbamoyl-3-methyl-4-{[1-phenyl-meth-(E)-ylidene]-amino}-butyric acid methyl ester
• CAS NO: 113273-88-4
• Molecular Weight: 318.416
• Mol File: 113273-88-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-tert-Butylcarbamoyl-3-methyl-4-{[1-phenyl-meth-(E)-ylidene]-amino}-butyric acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-tert-Butylcarbamoyl-3-methyl-4-{[1-phenyl-meth-(E)-ylidene]-amino}-butyric acid methyl ester(113273-88-4)
• EPA Substance Registry System: 4-tert-Butylcarbamoyl-3-methyl-4-{[1-phenyl-meth-(E)-ylidene]-amino}-butyric acid methyl ester(113273-88-4)

Safety Data

• Hazardous Substances Data: 113273-88-4(Hazardous Substances Data)

Upstream product

• 15678-99-6 N-tert-butylchloroacetamide 
• 71034-40-7 2-amino-N-(tert-butyl)acetamide 

Relevant articles and documents

Lithium Bromide/Triethylamine Induced Cycloaddition of N-Alkylidene 2-Amino Esters and Amides to Electron-Deficient Olefins with High Regio- and Stereoselectivity

The imines of 2-amino esters and amides derived from glycine, alanine, and valine are deprotonated by the action of a lithium halide and triethylamine (or DBU).The resulting anionic intermediates undergo highly regio- and stereoselective cycloadditions with a variety of olefins activated by carbonyl-type substituents to produce stereochemically defined derivatives of proline esters or amides.The scope and limitations of this novel cycloaddition are discussed.