113296-67-6Relevant academic research and scientific papers
Molecular Recognition of Polar Neutral Molecules by Metallomacrocycles: Synthesis, 1H NMR Spectroscopy, X-ray Structure, Electrochemistry, and Ab Initio Calculations
Doorn, Arie R. van,Schaafstra, Robert,Bos, Martinus,Harkema, Sybolt,Eerden, Johan van,et al.
, p. 6083 - 6094 (2007/10/02)
Metallomacrocycles 5 possessing an immobilized Lewis acidic uranyl group were synthesized by reaction of aldehydes 4 with cis-1,2-cyclohexanediamine in the presence of Ba2+ as a template cation and subsequent transmetallation with UO22+/s
Synthesis, Complexation, and X-Ray Structure of a New Type of Binucleating Macrocycle Incorporating Both Soft and Hard Ligating Sites
Staveren, Catherina J.,Reinhoudt, David N.,Eerden, Johan,Harkema, Sybolt
, p. 974 - 977 (2007/10/02)
A macrocyclic ligand with both a Schiff base moiety and a polyether cavity forms mono- and bi-nuclear complexes; X-ray analysis of the mononuclear Ba(ClO4)2 complex shows that Ba2+ is co-ordinated in the polyether cavity.
