113299-31-3

Basic information

• Product Name: rac-Carba-β-arabinofuranose
• CAS NO: 113299-31-3
• Molecular Weight: 148.159
• Mol File: 113299-31-3.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: rac-Carba-β-arabinofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: rac-Carba-β-arabinofuranose(113299-31-3)
• EPA Substance Registry System: rac-Carba-β-arabinofuranose(113299-31-3)

Safety Data

• Hazardous Substances Data: 113299-31-3(Hazardous Substances Data)

Upstream product

• 921770-96-9 tert-butyl-[(1R,4S)-4-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]cyclopent-2-en-1-oxy]dimethylsilane 
• 921771-03-1 (1S,2R,3S,4S)-2,3-Bis-benzyloxy-4-hydroxy-cyclopentanecarbaldehyde 
• 763105-46-0 (S)-(S)-4-(1,4-Dioxa-spiro[4.5]dec-2-yl)-cyclopent-2-enol 
• 305834-30-4 (1S,2S,3R,4R)-3-tert-butyldimethylsilyloxy-4-hydroxymethyl-1,2-O,O-(methylethylidenedioxy)cyclopentane 
• 112543-75-6 (3aR,4R,5R,6aS)-5-Hydroxymethyl-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-ol 
• 129885-83-2 (3aR,6R,6aR)-2,2-Dimethyl-6-trityloxymethyl-tetrahydro-cyclopenta[1,3]dioxol-4-one 
• 105265-91-6 (3aS,6aS)-4-Acetoxy-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxole-5,5-dicarboxylic acid dimethyl ester 
• 105265-92-7 methyl (3R,4S)-3,4-(isopropylidenedioxy)-1-cyclopentene-1-carboxylate 
• 105265-93-8 (3R,4S)-3,4-(isopropylidenedioxy)-1-cyclopentene-1-methanol 
• 112543-75-6 (3aR,4S,5S,6aS)-5-Hydroxymethyl-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-ol 
• 115384-58-2 6-<(methoxymethoxy)methyl>-2,2-dimethyl-3aβ,5,6α,6aβ-tetrahydro-4H-cyclopenta-1,3-dioxol-4-one 
• 133491-12-0 (3aS,4S,6R,6aR)-6-Methoxymethoxymethyl-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-ol 
• 132575-63-4 (3aR,6R,6aR)-6-(hydroxymethyl)-2,2-dimethyldihydro-3aH-cyclopenta[d][1,3]dioxol-4(5H)-one 
• 115509-13-2 (3aR,6aR)-2,2-Dimethyl-3a,6a-dihydro-cyclopenta[1,3]dioxol-4-one 

Relevant articles and documents

Synthesis of α- and β-D-carbaribofuranose from (+)-norborn-5-en-2-one

α- and β-D-carbaribofuranose 7 and 9, resp., are prepared from ( + )-norborn-5-en-2-one in a 6-step (8-step, resp.) synthetic sequence in 27% (13%, resp.) overall yield.

The cobalt-catalyzed oxygenative radical route from hexopyranosides to carbapentofuranoses

Cobalt-catalyzed radical cyclization/oxygenation of various 6-iodohex-1-enitols gave in one step the carbocyclic analogs of pentofuranoses. The reaction was run under very mild conditions and gave moderate to good yields of carbapentofuranoses within a few hours. All the possible 6-iodohex-1-enitol stereoisomers were prepared, and the influence of relative configurations and protecting groups was studied.

Synthesis of pseudo-Ribofuranoses by Stereocontrolled Reactions on 4-Hydroxycyclopent-2-enylmethanol Derivatives

The diol 3 is a major product formed from a Prins reaction on cyclopentadiene and was readily converted into the derivatives 4-7.The latter compounds were obtained in states of high optical purity by using both enzyme-catalysed hydrolysis and esterificati