113306-41-5Relevant articles and documents
Alternative Synthesis of (+/-)-Trisporol B wia (+/-)-6-Hydroxymethyl-2,6-dimethyl-2-cyclohexen-1-one
Takahashi, Shunya,Oritani, Takayuki,Yamashita, Kyohei
, p. 1143 - 1148 (2007/10/02)
(+/-)-Methyl 1,3-dimethyl-2-oxo-3-cyclohexene-1-carboxylate (7) was synthesized from methyl propionate via Claisen condensation followed by Robinson annelation with acrolein.Lithium aluminum hydride reduction and manganese dioxide oxidation of 7 gave (+/-