1133422-68-0Relevant academic research and scientific papers
Copper-catalyzed arylation of nucleophiles by using butadienylphosphines as ligands: Mechanistic insight
Kaddouri, Hamid,Vicente, Virginie,Ouali, Armelle,Ouazzani, Fouad,Taillefer, Marc
, p. 333 - 336 (2009)
(Figure Presented) Worth diene for: The butadienylphosphine L (see scheme), obtained on a large scale from a new synthetic method, is an efficient ligand in Ullmann-type copper-catalyzed arylation reactions. The use of this phosphorus ligand made it possible to follow the reaction by 31P NMR spectroscopy and thus to propose a mechanism for the Ullmann reaction.
METHOD FOR THE PREPARATION OF PHOSPHINE BUTADIENE LIGANDS, COMPLEXES THEREOF WITH COPPER AND USE THEREOF IN CATALYSIS
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Page/Page column 20, (2010/06/11)
The present invention relates to a method for preparing phosphine butadiene-type ligands, and their use, particularly as catalytic metal ligands used in the reactions leading to the formation of carbon-carbon and carbon-heteroatom bonds.
