1133471-36-9Relevant academic research and scientific papers
Intermolecular C-H and Si-H insertion reactions with halodiazoacetates
Bonge, Hanne Therese,Hansen, Tore
body text, p. 91 - 96 (2009/06/24)
Ethyl halodiazoacetates react with a range of substrates in regioselective rhodium(II)-catalysed C-H and Si-H insertion reactions giving α-halocarbonyl products in up to 82% yield. The halodiazoacetates are a novel class of diazo compounds that can undergo intermolecular carbenoid C-H insertion reactions, thus broadening the synthetic utility of such reactions. Georg Thieme Verlag Stuttgart.
