113348-33-7Relevant academic research and scientific papers
Cyano-phosphorylation of aldehydes catalyzed by a nucleophilic N-heterocyclic carbene
Fukuda, Yoshimasa,Maeda, Yuka,Kondo, Kazuhiro,Aoyama, Toyohiko
, p. 397 - 398 (2006)
The first method for cyano-phosphorylation of aldehydes with diethyl cyanophosphonate in the presence of N-heterocyclic carbene prepared from 1,3-bis(2,4,6-trimethylphenyl)imidazolium chloride and KOt-Bu, as a nucleophilic catalyst, is described.
Application of Cyanophosphates in Organic Synthesis. Reactivity of α-Cyano-α-diethylphosphonooxy Anions
Kurihara, Takushi,Santo, Kazunori,Harusawa, Shinya,Yoneda, Ryuji
, p. 4777 - 4788 (2007/10/02)
The utility of the cyanohydrin diethylphosphates derived from aldehydes (arylaldehydes,crotonaldehyde, and cinnamaldehyde) as an acyl anion equivalent was examined.Deprotonation of cyanophosphates with n-butyllithium in the presence of tetramethylethylene
