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Intramolecular Reactions of 1,5-Diaryl-1,5-pentadiyl Radicals
Peyman, Anuschirwan,Beckhaus, Hans-Dieter,Ruechardt, Christoph
, p. 1027 - 1032 (2007/10/02)
Photochemical decomposition of 2,6-diarylcyclohexanones 1a-d yields 1,2-diarylcyclopentanes 4 and 1,5-diaryl-1-pentenes 5 by intramolecular reaction of the intermediate 1,5-diaryl-1,5-pentadiyls 3.The two stereoisomers cis-4 and trans-4 are formed in equa
